The accuracy and limitations of a new meter used to measure aqueous carbon dioxide

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The OxyGuard CO(2) Analyzer is a novel meter that can directly measure aqueous CO(2) gas pressure using a water-resistant gas-permeable membrane and infra-red absorption cell. The pCO(2) is converted to a concentration via a solubility factor determined from the calibration procedure and a thermistor. We undertook to independently validate the precision and utility of this meter. Water flow over the probe membrane was a key determinant of the reaction time. At water velocities of >= 30 cm s(-1) the time to 99% span was 6-7 min, while at 0 cm s(-1) it was 55-60 min. Temperature and CO(2(aq)) concentration did not appreciably affect reaction time. The meter had a precision of +/- 0.5 mg L(-1) CO(2(aq)), and high linearity (correlation 0.99-1.01) above 1 mg L(-1) in both freshwater and seawater. The standard meter will not be useful for measuring low concentrations such as atmospheric CO(2) levels, but will be useful in situations where accurate pH and carbonate alkalinity determinations are difficult to obtain, such as saline waters and waters of high organic loadings. (C) 2010 Elsevier B.V. All rights reserved.
Original languageEnglish
JournalAquacultural Engineering
Volume43
Issue number3
Pages (from-to)101-107
Number of pages7
ISSN0144-8609
DOIs
Publication statusPublished - 1 Nov 2010

ID: 34358963