Pulse radiolysis study of CF3CCI2 and CF3CCI2O2 radicals in the gas phase at 295K

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Standard

Pulse radiolysis study of CF3CCI2 and CF3CCI2O2 radicals in the gas phase at 295K. / Wallington, T. J.; Ellermann, T.; Nielsen, OLE J.

I: Research on Chemical Intermediates, Bind 20, Nr. 3-5, 01.01.1994, s. 265-276.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Wallington, TJ, Ellermann, T & Nielsen, OLEJ 1994, 'Pulse radiolysis study of CF3CCI2 and CF3CCI2O2 radicals in the gas phase at 295K', Research on Chemical Intermediates, bind 20, nr. 3-5, s. 265-276. https://doi.org/10.1163/156856794X00333

APA

Wallington, T. J., Ellermann, T., & Nielsen, OLE. J. (1994). Pulse radiolysis study of CF3CCI2 and CF3CCI2O2 radicals in the gas phase at 295K. Research on Chemical Intermediates, 20(3-5), 265-276. https://doi.org/10.1163/156856794X00333

Vancouver

Wallington TJ, Ellermann T, Nielsen OLEJ. Pulse radiolysis study of CF3CCI2 and CF3CCI2O2 radicals in the gas phase at 295K. Research on Chemical Intermediates. 1994 jan. 1;20(3-5):265-276. https://doi.org/10.1163/156856794X00333

Author

Wallington, T. J. ; Ellermann, T. ; Nielsen, OLE J. / Pulse radiolysis study of CF3CCI2 and CF3CCI2O2 radicals in the gas phase at 295K. I: Research on Chemical Intermediates. 1994 ; Bind 20, Nr. 3-5. s. 265-276.

Bibtex

@article{215d629ae7e44b6898f260a2ba85ffac,
title = "Pulse radiolysis study of CF3CCI2 and CF3CCI2O2 radicals in the gas phase at 295K",
abstract = "The ultraviolet absorption spectra and self reaction kinetics of CF3CCI2 and CF3CCI2O2 radicals have been studied in the gas phase at 295K. Absorption cross sections were quantified over the wavelength range 220-300 nm. Measured cross sections near the absorption maxima were γCF3CCI2(230 nm) = (9.70 ± 1.47) x 10-18 and γCF3CCI2O2(250 nm) = (1.70 ± 0.26) x 10-18 cm2 molecule-1. Errors are statistical (2γ) together with our estimate of potential systematic errors. Rate constants for the self reaction of CF3CCI2 and CF3CCI2O2 radicals were measured to be k6 = (2.46 ± 0.43) x 10-12 and k7obs = (3.33 ± 0.53) x 10-12 cm3 molecule-1 s-1, respectively. Results are discussed with respect to the existing database concerning halogenated peroxy radicals.",
author = "Wallington, {T. J.} and T. Ellermann and Nielsen, {OLE J.}",
year = "1994",
month = jan,
day = "1",
doi = "10.1163/156856794X00333",
language = "English",
volume = "20",
pages = "265--276",
journal = "Research on Chemical Intermediates",
issn = "0922-6168",
publisher = "Springer Netherlands",
number = "3-5",

}

RIS

TY - JOUR

T1 - Pulse radiolysis study of CF3CCI2 and CF3CCI2O2 radicals in the gas phase at 295K

AU - Wallington, T. J.

AU - Ellermann, T.

AU - Nielsen, OLE J.

PY - 1994/1/1

Y1 - 1994/1/1

N2 - The ultraviolet absorption spectra and self reaction kinetics of CF3CCI2 and CF3CCI2O2 radicals have been studied in the gas phase at 295K. Absorption cross sections were quantified over the wavelength range 220-300 nm. Measured cross sections near the absorption maxima were γCF3CCI2(230 nm) = (9.70 ± 1.47) x 10-18 and γCF3CCI2O2(250 nm) = (1.70 ± 0.26) x 10-18 cm2 molecule-1. Errors are statistical (2γ) together with our estimate of potential systematic errors. Rate constants for the self reaction of CF3CCI2 and CF3CCI2O2 radicals were measured to be k6 = (2.46 ± 0.43) x 10-12 and k7obs = (3.33 ± 0.53) x 10-12 cm3 molecule-1 s-1, respectively. Results are discussed with respect to the existing database concerning halogenated peroxy radicals.

AB - The ultraviolet absorption spectra and self reaction kinetics of CF3CCI2 and CF3CCI2O2 radicals have been studied in the gas phase at 295K. Absorption cross sections were quantified over the wavelength range 220-300 nm. Measured cross sections near the absorption maxima were γCF3CCI2(230 nm) = (9.70 ± 1.47) x 10-18 and γCF3CCI2O2(250 nm) = (1.70 ± 0.26) x 10-18 cm2 molecule-1. Errors are statistical (2γ) together with our estimate of potential systematic errors. Rate constants for the self reaction of CF3CCI2 and CF3CCI2O2 radicals were measured to be k6 = (2.46 ± 0.43) x 10-12 and k7obs = (3.33 ± 0.53) x 10-12 cm3 molecule-1 s-1, respectively. Results are discussed with respect to the existing database concerning halogenated peroxy radicals.

UR - http://www.scopus.com/inward/record.url?scp=3943097508&partnerID=8YFLogxK

U2 - 10.1163/156856794X00333

DO - 10.1163/156856794X00333

M3 - Journal article

AN - SCOPUS:3943097508

VL - 20

SP - 265

EP - 276

JO - Research on Chemical Intermediates

JF - Research on Chemical Intermediates

SN - 0922-6168

IS - 3-5

ER -

ID: 228192823