Absolute rate constants for the reaction of NO3 radicals with a series of dienes at 295 K
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The rate constants for the reaction of NO3 radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3-pentadiene, trans,trans-2,4-hexadiene, and 1,3-cyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constant were obtained using the absolute technique of pulse radiolysis combined with kinetic UV-VIS spectroscopy. The results are discussed in terms of reactivity trends and previous literature data.
Original language | English |
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Journal | Chemical Physics Letters |
Volume | 200 |
Issue number | 3 |
Pages (from-to) | 224-229 |
Number of pages | 6 |
ISSN | 0009-2614 |
DOIs | |
Publication status | Published - 4 Dec 1992 |
ID: 228196707