Biomimetic studies of wood decay: Simulating the effect of low molecular weight compounds and fungal enzymes
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Biomimetic studies of wood decay: Simulating the effect of low molecular weight compounds and fungal enzymes. / Hastrup, Anne Christine Steenkjær; Howell, Caitlin; Jellison, Jody.
2007. Poster session presented at International Research Group on Wood Protection (IRG) 38th Annual Meeting, IRG, United States.Research output: Contribution to conference › Poster › Research
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TY - CONF
T1 - Biomimetic studies of wood decay: Simulating the effect of low molecular weight compounds and fungal enzymes
AU - Hastrup, Anne Christine Steenkjær
AU - Howell, Caitlin
AU - Jellison, Jody
N1 - Titel på proceedings: International Research Group on Wood Protection (IRG) 38<sup>th</sup> Annual Meeting Volume: IRG/WP 07 Udgave: IRG/WP 07-10622
PY - 2007
Y1 - 2007
N2 - The effect of FeCl3 (Fe3+), hydrogen peroxide (H2O2), a low molecular weight compound (2,3-Dihydroxybenzoic acid), and oxalic acid on wood were tested in a study designed to mimic wood degradationby brown rot fungi. Previous studies suggest that these components are involved in the early stages of brownrot decay where they catalyze the formation of hydroxyl radicals through the Fenton reaction or relatedmechanisms. However, the separate and combined effects of these individual chemical components on woodhave not been thoroughly investigated.Tests were conducted in Erlenmeyer flasks containing 50 ml of 40 mM acetate buffer (pH 4.5), white pinewood powder and varying combinations of the chemicals previously mentioned. Changes in cellulosecrystallinity were analyzed by X-ray diffraction using a ¿-2¿ scan. Findings suggest that iron, H2O2, chelatorsand oxalic acid may affect over all crystallinity and crystallite size. Understanding how these chemicals modifywood will facilitate characterization of the mechanisms involved in wood biodegradation by brown rot fungi.
AB - The effect of FeCl3 (Fe3+), hydrogen peroxide (H2O2), a low molecular weight compound (2,3-Dihydroxybenzoic acid), and oxalic acid on wood were tested in a study designed to mimic wood degradationby brown rot fungi. Previous studies suggest that these components are involved in the early stages of brownrot decay where they catalyze the formation of hydroxyl radicals through the Fenton reaction or relatedmechanisms. However, the separate and combined effects of these individual chemical components on woodhave not been thoroughly investigated.Tests were conducted in Erlenmeyer flasks containing 50 ml of 40 mM acetate buffer (pH 4.5), white pinewood powder and varying combinations of the chemicals previously mentioned. Changes in cellulosecrystallinity were analyzed by X-ray diffraction using a ¿-2¿ scan. Findings suggest that iron, H2O2, chelatorsand oxalic acid may affect over all crystallinity and crystallite size. Understanding how these chemicals modifywood will facilitate characterization of the mechanisms involved in wood biodegradation by brown rot fungi.
M3 - Poster
Y2 - 20 May 2007 through 24 May 2007
ER -
ID: 2967576