The accuracy and limitations of a new meter used to measure aqueous carbon dioxide
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The accuracy and limitations of a new meter used to measure aqueous carbon dioxide. / Moran, Damian; Tirsgård, Bjørn; Steffensen, John Fleng.
In: Aquacultural Engineering, Vol. 43, No. 3, 01.11.2010, p. 101-107.Research output: Contribution to journal › Journal article › Research › peer-review
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TY - JOUR
T1 - The accuracy and limitations of a new meter used to measure aqueous carbon dioxide
AU - Moran, Damian
AU - Tirsgård, Bjørn
AU - Steffensen, John Fleng
PY - 2010/11/1
Y1 - 2010/11/1
N2 - The OxyGuard CO(2) Analyzer is a novel meter that can directly measure aqueous CO(2) gas pressure using a water-resistant gas-permeable membrane and infra-red absorption cell. The pCO(2) is converted to a concentration via a solubility factor determined from the calibration procedure and a thermistor. We undertook to independently validate the precision and utility of this meter. Water flow over the probe membrane was a key determinant of the reaction time. At water velocities of >= 30 cm s(-1) the time to 99% span was 6-7 min, while at 0 cm s(-1) it was 55-60 min. Temperature and CO(2(aq)) concentration did not appreciably affect reaction time. The meter had a precision of +/- 0.5 mg L(-1) CO(2(aq)), and high linearity (correlation 0.99-1.01) above 1 mg L(-1) in both freshwater and seawater. The standard meter will not be useful for measuring low concentrations such as atmospheric CO(2) levels, but will be useful in situations where accurate pH and carbonate alkalinity determinations are difficult to obtain, such as saline waters and waters of high organic loadings. (C) 2010 Elsevier B.V. All rights reserved.
AB - The OxyGuard CO(2) Analyzer is a novel meter that can directly measure aqueous CO(2) gas pressure using a water-resistant gas-permeable membrane and infra-red absorption cell. The pCO(2) is converted to a concentration via a solubility factor determined from the calibration procedure and a thermistor. We undertook to independently validate the precision and utility of this meter. Water flow over the probe membrane was a key determinant of the reaction time. At water velocities of >= 30 cm s(-1) the time to 99% span was 6-7 min, while at 0 cm s(-1) it was 55-60 min. Temperature and CO(2(aq)) concentration did not appreciably affect reaction time. The meter had a precision of +/- 0.5 mg L(-1) CO(2(aq)), and high linearity (correlation 0.99-1.01) above 1 mg L(-1) in both freshwater and seawater. The standard meter will not be useful for measuring low concentrations such as atmospheric CO(2) levels, but will be useful in situations where accurate pH and carbonate alkalinity determinations are difficult to obtain, such as saline waters and waters of high organic loadings. (C) 2010 Elsevier B.V. All rights reserved.
U2 - 10.1016/j.aquaeng.2010.07.003
DO - 10.1016/j.aquaeng.2010.07.003
M3 - Journal article
VL - 43
SP - 101
EP - 107
JO - Aquacultural Engineering
JF - Aquacultural Engineering
SN - 0144-8609
IS - 3
ER -
ID: 34358963